Dicaesium diaquabis(methylenediphosphonato-κ2 O,O′)cobaltate(II)
نویسندگان
چکیده
The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl-enediphospho-nate ligand and one water mol-ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octa-hedrally coordinated by six O atoms with Cs-O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O-H⋯O hydrogen bonds.
منابع مشابه
Disodium diaquabis(methylenediphosphonato-κ2 O,O′)cobaltate(II) dihydrate
In the title compound, Na(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)]·2H(2)O, the asymmetric unit is composed of one methyl-enediphospho-nate ligand and one water mol-ecule, which both are coordinated to a Co(II) atom, as well as a non-coordinated water mol-ecule and a sodium cation. The Co(II) atom occupies a special position on a crystallographic inversion centre. The slightly distorted Co(II)O(6) oct...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011